混合原油的甾萜类和多环芳烃标志物短期风化规律研究

贺世杰; 王传远; 韩彬; 于洪军

doi:10.3969/j.issn.0253-4193.2015.02.001

混合原油的甾萜类和多环芳烃标志物短期风化规律研究

doi: 10.3969/j.issn.0253-4193.2015.02.001

1.
鲁东大学海岸研究所, 山东烟台 264025;中国科学院烟台海岸带研究所, 山东烟台 264003;中国科学院大学, 北京 100049
2.
中国科学院烟台海岸带研究所, 山东烟台 264003
3.
国家海洋局第一海洋研究所, 山东青岛 266061

基金项目: 国家自然科学基金资助项目(41206089,40806048);中国科学院(烟台台海岸带所)135课题培育项目—海岸带灾害风险与预警(Y455011031);中国科协政策研究类课题资助:我国近海养殖水域环境污染问题研究(2010JYXC-8).

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出版历程
- 收稿日期: 2014-04-11
- 修回日期: 2014-05-23

Effect of short-time weathering on biomarker ratios of terpanes, steranes and PAHs in two different mixing oils

1.
Coast Institute, Ludong University, Yantai 264025, China;Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003, China;University of Chinese Academy of Sciences, Beijing 100049, China
2.
Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003, China
3.
First Institute of Oceanography, State Oceanic Administration, Qingdao 266061, China

摘要

摘要: 将胜利和塔西两种原油以不同比例混合后置于人工气候箱进行风化模拟实验,采用气相色谱质谱联用仪(GC-MS) 检测风化样品中的生物标志化合物,探讨和揭示短期风化作用对混合溢油常用的甾萜类和多环芳烃诊断指标的影响.结果表明经过15 d的短期风化,在混源比例大于10%时,各系列混合油样的甾萜类生物标志物诊断指标与单一油品的相关诊断比值的差异性和混源油品比例值呈明显正相关.各系列混合油样中的常用萘及烷基萘等指标不适宜作为短期溢油来源鉴别的指标,但可以作为溢油是否发生混合的间接判定指标.根据常用的多环芳烃相关诊断指标,可将各系列油样的短期风化模式依据混源油品中塔西油田原油所占比例大致分为3类(20%~50%、10%和0%).多环芳烃系列诊断指标的相对标准偏差(RSD%)与混源油品比例有关,混源塔西油样的比例越高,PAHs系列指标的RSD%越大,稳定性越差.
- 混合原油 /
- 甾萜烷 /
- 多环芳烃 /
- 短期风化 /
- 诊断比值
Abstract: Oil collected from Tarim oilfield was poured with different proportions into oil collected from Shengli oilfield. The mixed oil samples were placed in an artificial climate chamber to simulate a short term weathering process and reveal short-term weathering effects on conventional biomarker diagnostic indicators of terpenes, steroids and PAHs(polycyclic aromatic hydrocarbons)in these mixed oil samples. When the mixing ratio is more than 10%, the diversity of terpenes and steroids diagnostic indicators between mixed oils samples and single samples is positively correlated with the pour weight ratios. The fact that substantial changes after weathering process have happened in conventional ratios of naphthalene and alkyl naphthalene in these series of mixed oil samples indicates that these ratios are unsuitable as short term indicators, but they can be used to determine indirectly whether an oil spill occurred are mixed or not. According to short-term weathering patterns of conventional PAHs ratios, these series of mixed oil samples can be broadly divided into three categories: 0%, 10% and 20%-50%. The stability of RSD% of PAHs ratios in these series of oil samples are negatively correlated to the pour weight ratios.
- mixed oils /
- Biomarker of terpanes /
- steranes and PAHs /
- short-term weathering simulation experiment /
- diagnostic ratios

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参考文献(46)

Woolgar L. Assessing the increasing risk of marine oil pollution spills in China [C]//Proceedings of International Oil Spill Conference. Savannah,GA,USA: American Petroleum Institute,2008,1: 711-715.

王传远,贺世杰,李延太,等. 中国海洋溢油污染现状及其生态影响研究[J]. 海洋科学,2009,33(6): 57-60. Wang Chuanyuan,He Shijie,Li Yantai,et al. Study on the state and ecological effect of spilled oil pollution in Chinese Coastal Waters[J]. Marine Science,2009,33(6): 57-60.

罗霞,马启敏,张传松. 短期风化作用下轻质原油化学组成的变化[J]. 海洋环境科学,2008,27(2): 173-177. Luo Xia,Ma Qimin,Zhang Chuansong. Changes of chemical composition of light crude oil weathered in short term[J]. Marine Environmental Science,2008,27(2): 173-177.

程海鸥,马启敏,肖晓彤. 船舶燃料油中主要多环芳烃的短期风化特性[J]. 环境化学,2009,28(5): 661-665. Cheng Haiou,Ma Qimin,Xiao Xiaotong. Study on weathering features of polycyclic aromatic hydrocarbons in ship fuel oil[J]. Environmental Chemistry,2009,28(5): 661-665.

李芸,李思源,杨万颖,等. 短期风化对溢油组成的影响[J]. 海洋环境科学,2010,29(4): 516-520. Li Yun,Li Siyuan,Yang Wanying,et al. Effect of short-time weathering on spilled oil composition[J].Marine Environmental Science,2010,29(4): 516-520.

曹磊,韩彬,郑立,等. 短期风化条件下渤海中部原油中PAHs风化规律研究[J]. 海洋环境科学,2011,30(3): 349-354. Cao Lei,Han Bin,Zheng Li,et al. Weathered regulation of polycyclic aromatic hydrocarbons (PAHs) in crude oil of central Bohai Sea in short-term[J]. Marine Environmental Science,2011,30(3): 349-354.

Yang C,Wang Z D,Hollebone B,et al. Application of light petroleum biomarkers for forensic characterization and source identification of spilled light refined oils[J]. Environmental Forensics,2012,13(4): 298-311.

Liu Z F,Liu J Q,Zhu Q Z,et al. The weathering of oil after the Deepwater Horizon oil spill: insights from the chemical composition of the oil from the sea surface,salt marshes and sediments [J]. Environmental Research Letters,2012,7(3): 035302.

Bao M T,Wang L N,Sun P Y,et al. Biodegradation of crude oil using an efficient microbial consortium in a simulated marine environment[J]. Marine Pollution Bulletin,2012,64(6): 1177-1185.

De Dominicis M,Pinardi N,Zodiatis G,et al. MEDSLIK-II,a Lagrangian marine oil spill model for short-term forecasting-Part 2: Numerical simulations and validations[J]. Geoscientific Model Development Discussions,2013,6(1): 1999-2043.

Radovic J R,Aeppli C,Nelson R K,et al. Assessment of photochemical processes in marine oil spill fingerprinting[J]. Marine Pollution Bulletin,2013,79(1/2): 268-277.

Zhou Z Z,Guo L,Shiller A M,et al. Characterization of oil components from the Deepwater Horizon oil spill in the Gulf of Mexico using fluorescence EEM and PARAFAC techniques[J]. Marine Chemistry,2013,148: 10-21.

Zhou Z Z,Liu Z F,Guo L D. Chemical evolution of Macondo crude oil during laboratory degradation as characterized by fluorescence EEMs and hydrocarbon composition[J]. Marine Pollution Bulletin,2013,66(1/2): 164-175.

Wang Z D,Yang C,Yang Z,et al. Forensic fingerprinting and source identification of the 2009 Sarnia (Ontario) oil spill[J]. Journal of Environmental Monitoring,2011,13(11): 3004-3017.

Li Y,Xiong Y Q. Identification and quantification of mixed sources of oil spills based on distributions and isotope profiles of long-chain n-alkanes[J]. Marine Pollution Bulletin,2009,58(12): 1868-1873.

刘星,王震,马新东,等. 典型消油剂对溢油鉴别生物标志物指示作用的影响[J]. 环境化学,2010,29(2): 299-304. Liu Xing,Wang Zhen,Ma Xindong,et al. Influence of typical dispersants on the effectiveness of Biomarkers of oil spills[J]. Environmental Chemistry,2010,29(2): 299-304.

刘星,王震,马新东,等. 海面溢油样品指纹解析[J]. 环境化学,2012,31(7): 952-957. Liu Xing,Wang Zhen,Ma Xindong,et al. Study on the fingerprints of spilled on the sea[J]. Environmental Chemistry,2012,31(7): 952-957.

Joo C,Shim W J,Kim G B,et al. Mesocosm study on weathering characteristics of Iranian Heavy crude oil with and without dispersants[J]. Journal of Hazardous Materials,2013,248-249: 37-46.

Prince R C,McFarlin K M,Butler J D,et al. The primary biodegradation of dispersed crude oil in the sea[J]. Chemosphere,2013,90(2): 521-526.

梁宏斌,张敏,王东良,等. 冀中坳陷苏桥—文安地区混源油定量识别模式研究——典型原油混合实验及混源油识别模式[J]. 沉积学报,2005,22(4): 689-693. Liang Hongbin,Zhang Min,Wang Dongliang,et al. Quantitative identification model of mixed oils from Suqiao-wenan area in Jidong depression: mixed experiment of typical oils and identification model of mixed oils[J]. Acta Sedimentologica Sinica,2005,22(4): 689-693.

李洪波,张敏,陈小慧. 松辽盆地南部梨树断陷混源油定量识别模式研究[J]. 石油天然气学报,2013,34(11): 1-7. Li Hongbo,Zhang Min,Chen Xiaohui. Quantitative identification mode of mixed oil from lishu fault depression in southern Songliao basin[J]. Journal of Oil and Gas Technology,2013,34(11): 1-7.

陈建平,邓春萍,宋孚庆,等. 用生物标志物定量计算混合原油油源的数学模型[J]. 地球化学,2007,36(2): 205-214. Chen Jianping,Deng Chunping,Song Fuqing,et al. Mathematical calculating mode using biomarkers to quantitatively determine relative source proportion of mixed oils[J]. Geochemica,2007,36(2): 205-214.

赵春花,王积宝,朱扬明. 混源生物降解油油源贡献率计算方法[J]. 石油实验地质,2010,32(2): 196-200,204. Zhao Chunhua,Wang Jibao,Zhu Yangming. The calculation method for the contribution rate of the biodegraded mixed-source oils[J]. Petroleum Geology and Experiment,2010,32(2): 196-200,204.

Stout S A,Uhler A D,Mccarthy K J,et al. A strategy and methodology for defensibly correlating spilled oil to source candidates[J]. Environment Forensics,2001,2(1): 87-98.

徐恒振,周传光,马永安,等. 萜烷作为溢油指示物(或指标)的研究[J]. 交通环保,2001,22(4): 15-20. Xu Hengzhen,Zhou Chuanguang,Ma Yongan,et al. Study on terpanes as the indicators of spilled oil[J]. Environmental Protection in Transportation,2001,22(4): 15-20.

徐恒振,周传光,马永安,等. 甾烷作为溢油指示物(或指标)的研究[J]. 海洋环境科学,2002,21(1): 13-20. Xu Hengzhen,Zhou Chuanguang,Ma Yongan,et al. Study on steranes as an indicator of oil spills[J]. Marine Environmental Science,2002,21(1): 13-20.

孙培艳,高振会,崔文林. 油指纹鉴别技术发展及应用[M]. 北京: 海洋出版社,2007. Sun Peiyan,Gao Zhenhui,Cui Wenlin. The oil development of fingerprint identification technology and Application[M]. Beijing: China Ocean Press,2007.

王传远,侯西勇,贺世杰,等. 甾萜烷和多环芳烃在风化溢油鉴别中的应用研究[J]. 海洋环境科学,2010,29(3): 297-302. Wang Chuanyuan,Hou Xiyong,He Shijie,et al. Application of identification of weathered spilled oils by terpane,sterane and polycyclic aromatic hydrocarbon[J]. Marine Environmental Science,2010,29(3): 297-302.

Wang C Y,Chen B,Zhang B Y,et ating on maturity parameters[J]. Petroleum Geology and Experiment,2007,29(4): 183-187.

Kruge M A. Determination of thermal maturity and organic matter type by principal components analysis of the distributions of polycyclic aromatic compounds[J]. International Journal of Coal Geology,2000,43(1): 27-51.

Lehne E,Dieckmann V. Improved understanding of mixed oil in Nigeria based on pyrolysis of asphaltenes[J]. Organic Geochemistry,2010,41(7): 661-674.

Wang Z D,Fingas M,Lambert P,et al. Characterization and identification of the Detroit River mystery oil spill (2002) [J]. Journal of Chromatography A,2004,1038 (1/2): 201-214.uiliano M,Doumenq P,et al. Long term evolution of petroleum biomarkers in mangrove soil (Guadeloupe)[J]. Marine Pollution Bulletin,1997,34(11): 868-874.

Wang Z D,Yang C,Parrott J L,et al. Forensic source differentiation of petrogenic,pyrogenic,and biogenic hydrocarbons in Canadian oil sands environmental samples[J]. Journal of Hazardous Materials,2014,271: 166-177.

赵玉慧,孙培艳,王馨平,等. 多环芳烃指纹用于渤海采油平台原油的鉴别[J]. 色谱,2008,26(1): 43-49. Zhao Yuhui,Sun Peiyan,Wang Xinping,et al. Identification of crude oils in Bohai Sea by polycyclic aromatic hydrocarbon fingerprints[J]. Chinese Journal of Chromatography,2008,26(1): 43-49.

倪张林,马启敏,富丽锟,等. 利用GC和GC/MS对溢油风化的鉴定[J]. 环境化学,2008,27(2): 256-259. Ni Zhanglin,Ma Qimin,Fu Likun,et al. Study on the oil spill weathering and identification by GC and GC/MS[J]. Environmental Chemistry,2008,27(2): 256-259.

Sauer T C,Michel J,Hayes M O,et al. Hydrocarbon characterization and weathering of oiled intertidal sediments along the Saudi Arabian Coast two years after the Gulf War oil spill[J]. Environment International,1998,24(1/2): 43-60.

Bernabeu A M,Fernández-Fernández S,Bouchette F,et al. Recurrent arrival of oil to Galician coast: The final step of the Prestige deep oil spill[J]. Journal of Hazardous Materials,2013,250-251: 82-90.

Radke M,Rullkötter J,Vriend S P. Distribution of naphthalenes in crude oils from the Java Sea: source and maturation effects[J]. Geochimica et Cosmochimica Acta,1994,58(17): 3675-3689.

Radke M,Welte D H,Willsch H. Maturity parameters based on aromatic hydrocarbons: influence of the organic matter type[J]. Organic Geochemistry,1986,10(1/3): 51-63.

Dutkiewicz A,Volk H,Ridley J,et al. Geochemistry of oil in fluid inclusions in a middle Proterozoic igneous intrusion: implications for the source of hydrocarbons in crystalline rocks[J]. Organic Geochemistry,2004,35(8): 937-957.

郑朝阳,柳益群,段毅,等. 塔河油田原油芳烃地球化学特征与运移研究[J]. 西北大学学报(自然科学版),2011,41(4): 653-657. Zheng Chaoyang ,Liu Yiqun ,Duan Yi,et al. Study on geochemical characteristics and migration of aromatic hydrocarbon of oils in Tahe Oilfield[J]. Journal of Northwest University (Natural Science),2011,41(4): 653-657.

王传远,贺世杰,王敏,等. 海洋风化溢油鉴别中特殊芳烃标志物的应用[J]. 环境化学,2009,28(3): 427-431. Wang Chuanyuan,He Shijie,Wang Min,et al. Identification of weathered crude oils by aromatic hydrocarbon fingerprinting[J]. Environmental Chemistry,2009,28(3): 427-431.

Xu Y H,Wang T G,Chen N X,et al. DBT parameters and dynamic monitoring during reservoir development,and distribution region prediction of remaining oil: A case study on the Sha-33 oil reservoir in the Liubei region,Nanpu sag[J]. Science China: Earth Sciences,2012,55(12): 2018-2025.

张立平,黄第藩. 某些海相烃源岩中多环芳烃的组成特征[J]. 石油勘探与开发,1997,24(2): 10-14. Zhang Liping,Huang Difan. Characteristics of polycyclic aromatic hydrocarbon associations in some marine source Rocks[J]. Petroleum Exploration and Development,1997,24(2): 10-14.

朱战军,江永健,程喆. 利用芳烃化合物评价烃源岩成熟度——以松辽盆地东岭区块为例[J]. 石油勘探与开发,2009,36(6): 790-796. Zhu Zhanjun,Jiang Yongjian,Cheng Zhe. Evaluating maturity of source rocks by aromatic compounds: A case from Dongling Block,Songliao Basin[J]. Petroleum Exploration and Development,2009,36(6): 790-796.

宋长玉,金洪蕊,刘璇. 烃源岩中甲基菲的分布及对成熟度参数的影响[J]. 石油实验地质,2007,29(4): 183-187. Song Changyu,Jin Hongrui,Liu Xuan. Distribution of methyl phenanthrene in sediments and its impac

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